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Author
Lobodin, V.V. ; Maksimova, E.V. ; Rodgers, R.P.
Title
Gas Chromatography/Atmospheric Pressure Chemical Ionization Tandem Mass Spectrometry for Fingerprinting the Macondo Oil Spill
Type
$loc['typeJournal Article']
Year
2016
Publication
Analytical Chemistry
Abbreviated Journal
Anal Chem
Volume
88
Issue
13
Pages
6914-6922
Keywords
Abstract
We report the first application of a new mass spectrometry technique (gas chromatography combined to atmospheric pressure chemical ionization tandem mass spectrometry, GC/APCI-MS/MS) for fingerprinting a crude oil and environmental samples from the largest accidental marine oil spill in history (the Macondo oil spill, the Gulf of Mexico, 2010). The fingerprinting of the oil spill is based on a trace analysis of petroleum biomarkers (steranes, diasteranes, and pentacyclic triterpanes) naturally occurring in crude oil. GC/APCI enables soft ionization of petroleum compounds that form abundant molecular ions without (or little) fragmentation. The ability to operate the instrument simultaneously in several tandem mass spectrometry (MS/MS) modes (e.g., full scan, product ion scan, reaction monitoring) significantly improves structural information content and sensitivity of analysis. For fingerprinting the oil spill, we constructed diagrams and conducted correlation studies that measure the similarity between environmental samples and enable us to differentiate the Macondo oil spill from other sources.
Address
National High Magnetic Field Laboratory, Florida State University , 1800 East Paul Dirac Drive, Tallahassee, Florida 32310, United States
Corporate Author
Thesis
Publisher
Place of Publication
Editor
Language
English
Summary Language
Original Title
Series Editor
Series Title
Abbreviated Series Title
Series Volume
Series Issue
Edition
ISSN
0003-2700
ISBN
Medium
Area
Expedition
Conference
Funding
PMID:27281271
Approved
$loc['no']
Call Number
COAPS @ mfield @
Serial
40
Permanent link to this record
Author
Lombardi, K. C.
Title
Resolving the Diurnal and Synoptic Variance of Scatterometer Vector Wind Observations
Type
$loc['typeManuscript']
Year
2004
Publication
Abbreviated Journal
Volume
Issue
Pages
Keywords
Rotary Spectra, Least Squares Regression, QSCAT, Midori2, Oceanic Winds
Abstract
Scatterometer observations of vector winds are used to examine the amplitudes of synoptic and diurnal cycles. Scatterometers have the advantage of providing global coverage over water; however, irregular temporal sampling complicates the analyses. A least squares technique is used in determination of the amplitudes and phases of the diurnal and synoptic cycles on spatial scales of 5°, 15°, and 30°. In open ocean areas and regions with sufficient open water, the magnitudes of the diurnal and synoptic cycles are 1.0 ms-1 and 3.5ms-1, respectively. Diurnal amplitudes are highest in the polar regions and close to land surfaces due to sea breeze effects. The fraction of variance explained by the diurnal cycle is greatest near the equator. Synoptic amplitudes are consistently larger downwind of land from storm tracks and in the southern polar region as the time analyzed is during the southern winter season.
Address
Department of Meteorology
Corporate Author
Thesis
$loc['Master's thesis']
Publisher
Florida State University
Place of Publication
Tallahassee, FL
Editor
Language
Summary Language
Original Title
Series Editor
Series Title
Abbreviated Series Title
Series Volume
Series Issue
Edition
ISSN
ISBN
Medium
Area
Expedition
Conference
Funding
NASA, OSU
Approved
$loc['no']
Call Number
COAPS @ mfield @
Serial
624
Permanent link to this record
Author
López, M. ; Zamudio, L. ; Padilla, F.
Title
Effects of the 1997-1998 El Niño on the exchange of the northern Gulf of California
Type
$loc['typeJournal Article']
Year
2005
Publication
Journal of Geophysical Research
Abbreviated Journal
J. Geophys. Res.
Volume
110
Issue
C11
Pages
Keywords
Abstract
Address
Corporate Author
Thesis
Publisher
Place of Publication
Editor
Language
Summary Language
Original Title
Series Editor
Series Title
Abbreviated Series Title
Series Volume
Series Issue
Edition
ISSN
0148-0227
ISBN
Medium
Area
Expedition
Conference
Funding
Approved
$loc['no']
Call Number
COAPS @ mfield @
Serial
447
Permanent link to this record
Author
Lowry, M. R.
Title
Developing a Unified Superset in Quantifying Ambiguities Among Tropical Cyclone Best Track Data for the Western North Pacific
Type
$loc['typeManuscript']
Year
2009
Publication
Abbreviated Journal
Volume
Issue
Pages
Keywords
Abstract
In the western North Pacific basin, several agencies archive “best track” data of tropical cyclones. The Joint Typhoon Warning Center (JTWC) in Hawaii is responsible for the issuance of tropical cyclone warnings for United States Department of Defense interests and has a record of tropical cyclones extending back to 1945. The Japanese Meteorological Agency (JMA) is the World Meteorological Organization (WMO) official Regional Specialized Meteorological Center (RSMC) for the western North Pacific basin and has best track tropical cyclone data extending back to 1951. The Shanghai Typhoon Institute (STI) of the Chinese Meteorological Administration and the Hong Kong Observatory (HKO) of the Government of the Hong Kong Special Administrative Region also have 6-hourly tropical cyclone data records from 1949 and 1961, respectively. Western North Pacific (WNP) data sets are investigated in order to quantify ambiguities in position and intensity estimates among the forecast institutions through the development of a unified Superset. Ambiguities among the two primary warning centers (JMA and JTWC) are presented in the context of a changing observation network, observational tools, and analysis techniques since the beginning of tropical cyclone records. Mean differences in position estimates are found between the two centers on the order of 60 km prior to the introduction of meteorological satellites in 1961 and near 50 km following the deactivation of aircraft reconnaissance in 1987. Results show a step function change among intensity in JTWC and JMA best track data from 1989 to 1990 due to varying applications of the Dvorak intensity estimation technique. Parsing best track data into landfall subsets does not ameliorate interagency differences in position or intensity estimates. Additionally, analyses from Superset data call into question the veracity of JTWC best track data during the period from 1995-1999. The applicability of adopting an individual data set in discerning long term climate trends is examined in light of these differences. Past efforts to analyze, assemble, and maintain a complete, reliable best track tropical cyclone data set for the WNP are discussed among topical methods of incorporating the Superset within a basin-wide re-analysis.
Address
Department of Meteorology
Corporate Author
Thesis
$loc['Master's thesis']
Publisher
Florida State University
Place of Publication
Tallahassee, FL
Editor
Language
Summary Language
Original Title
Series Editor
Series Title
Abbreviated Series Title
Series Volume
Series Issue
Edition
ISSN
ISBN
Medium
Area
Expedition
Conference
Funding
Approved
$loc['no']
Call Number
COAPS @ mfield @
Serial
605
Permanent link to this record
Author
Lu, J. ; Chassignet, E. P. ; Yin, J. ; Misra, V. ; Michael, J.-P.
Title
Comparison of HYCOM and POP models in the CCSM3.0 Framework. Part I: Modes of climate variability beyond ENSO
Type
$loc['typeManuscript']
Year
2013
Publication
Abbreviated Journal
Volume
Issue
Pages
submitted
Keywords
Abstract
Address
Corporate Author
Thesis
Publisher
Place of Publication
Editor
Language
Summary Language
Original Title
Series Editor
Series Title
Abbreviated Series Title
Series Volume
Series Issue
Edition
ISSN
ISBN
Medium
Area
Expedition
Conference
Funding
Approved
$loc['no']
Call Number
COAPS @ mfield @
Serial
219
Permanent link to this record
Author
Lu, J. ; Hu, A. ; Zeng, Z.
Title
On the possible interaction between internal climate variability and forced climate change
Type
$loc['typeJournal Article']
Year
2014
Publication
Geophysical Research Letters
Abbreviated Journal
Geophys. Res. Lett.
Volume
41
Issue
8
Pages
2962-2970
Keywords
climate variability ; forced climate change ; global warming hiatus ; Atlantic Multidecadal Variability (AMV) ; Pacific Decadal Oscillation (PDO)
Abstract
Address
Corporate Author
Thesis
Publisher
Place of Publication
Editor
Language
Summary Language
Original Title
Series Editor
Series Title
Abbreviated Series Title
Series Volume
Series Issue
Edition
ISSN
0094-8276
ISBN
Medium
Area
Expedition
Conference
Funding
Approved
$loc['no']
Call Number
COAPS @ mfield @
Serial
138
Permanent link to this record
Author
Lu, J. ; Wang, F. ; Liu, H. ; Lin, P.
Title
Stationary mesoscale eddies, upgradient eddy fluxes, and the anisotropy of eddy diffusivity
Type
$loc['typeJournal Article']
Year
2016
Publication
Geophysical Research Letters
Abbreviated Journal
Geophys. Res. Lett.
Volume
43
Issue
2
Pages
743-751
Keywords
Abstract
Address
Corporate Author
Thesis
Publisher
Place of Publication
Editor
Language
Summary Language
Original Title
Series Editor
Series Title
Abbreviated Series Title
Series Volume
Series Issue
Edition
ISSN
0094-8276
ISBN
Medium
Area
Expedition
Conference
Funding
Approved
$loc['no']
Call Number
COAPS @ mfield @
Serial
41
Permanent link to this record
Author
Luecke, C.A. ; Arbic, B.K. ; Bassette, S.L. ; Richman, J.G. ; Shriver, J.F. ; Alford, M.H. ; Smedstad, O.M. ; Timko, P.G. ; Trossman, D.S. ; Wallcraft, A.J.
Title
The Global Mesoscale Eddy Available Potential Energy Field in Models and Observations
Type
$loc['typeJournal Article']
Year
2017
Publication
Journal of Geophysical Research: Oceans
Abbreviated Journal
J. Geophys. Res. Oceans
Volume
122
Issue
11
Pages
9126-9143
Keywords
eddy available potential energy ; mesoscale eddies ; mixing ; model-data comparison ; ocean energy reservoirs ; Argo
Abstract
Address
Corporate Author
Thesis
Publisher
Place of Publication
Editor
Language
Summary Language
Original Title
Series Editor
Series Title
Abbreviated Series Title
Series Volume
Series Issue
Edition
ISSN
2169-9275
ISBN
Medium
Area
Expedition
Conference
Funding
Approved
$loc['no']
Call Number
COAPS @ mfield @
Serial
464
Permanent link to this record
Author
Luecke, C.A. ; Arbic, B.K. ; Bassette, S.L. ; Richman, J.G. ; Shriver, J.F. ; Alford, M.H. ; Smedstad, O.M. ; Timko, P.G. ; Trossman, D.S. ; Wallcraft, A.J.
Title
The Global Mesoscale Eddy Available Potential Energy Field in Models and Observations: GLOBAL LOW-FREQUENCY EDDY APE
Type
$loc['typeJournal Article']
Year
2017
Publication
Journal of Geophysical Research: Oceans
Abbreviated Journal
J. Geophys. Res. Oceans
Volume
122
Issue
11
Pages
9126-9143
Keywords
eddy available potential energy ; mesoscale eddies ; mixing ; model‐ ; data comparison ; ocean energy reservoirs ; Argo
Abstract
Global maps of the mesoscale eddy available potential energy (EAPE) field at a depth of 500 m are created using potential density anomalies in a high‐resolution 1/12.5° global ocean model. Maps made from both a free‐running simulation and a data‐assimilative reanalysis of the HYbrid Coordinate Ocean Model (HYCOM) are compared with maps made by other researchers from density anomalies in Argo profiles. The HYCOM and Argo maps display similar features, especially in the dominance of western boundary currents. The reanalysis maps match the Argo maps more closely, demonstrating the added value of data assimilation. Global averages of the simulation, reanalysis, and Argo EAPE all agree to within about 10%. The model and Argo EAPE fields are compared to EAPE computed from temperature anomalies in a data set of “moored historical observations” (MHO) in conjunction with buoyancy frequencies computed from a global climatology. The MHO data set allows for an estimate of the EAPE in high‐frequency motions that is aliased into the Argo EAPE values. At MHO locations, 15–32% of the EAPE in the Argo estimates is due to aliased motions having periods of 10 days or less. Spatial averages of EAPE in HYCOM, Argo, and MHO data agree to within 50% at MHO locations, with both model estimates lying within error bars observations. Analysis of the EAPE field in an idealized model, in conjunction with published theory, suggests that much of the scatter seen in comparisons of different EAPE estimates is to be expected given the chaotic, unpredictable nature of mesoscale eddies.
Address
Corporate Author
Thesis
Publisher
Place of Publication
Editor
Language
Summary Language
Original Title
Series Editor
Series Title
Abbreviated Series Title
Series Volume
Series Issue
Edition
ISSN
2169-9275
ISBN
Medium
Area
Expedition
Conference
Funding
Approved
$loc['no']
Call Number
COAPS @ rl18 @
Serial
992
Permanent link to this record
Author
MacKinnon, J.A. ; Alford, M.H. ; Ansong, J.K. ; Arbic, B.K. ; Barna, A. ; Briegleb, B.P. ; Bryan, F.O. ; Buijsman, M.C. ; Chassignet, E.P. ; Danabasoglu, G. ; Diggs, S. ; Griffies, S.M. ; Hallberg, R.W. ; Jayne, S.R. ; Jochum, M. ; Klymak, J.M. ; Kunze, E. ; Large, W.G. ; Legg, S. ; Mater, B. ; Melet, A.V. ; Merchant, L.M. ; Musgrave, R. ; Nash, J.D. ; Norton, N.J. ; Pickering, A. ; Pinkel, R. ; Polzin, K. ; Simmons, H.L. ; St. Laurent, L.C. ; Sun, O.M. ; Trossman, D.S. ; Waterhouse, A.F. ; Whalen, C.B. ; Zhao, Z.
Title
Climate Process Team on Internal-Wave Driven Ocean Mixing
Type
$loc['typeJournal Article']
Year
2017
Publication
Bulletin of the American Meteorological Society
Abbreviated Journal
Bull. Amer. Meteor. Soc.
Volume
98
Issue
11
Pages
2429-2454
Keywords
Abstract
Address
Corporate Author
Thesis
Publisher
Place of Publication
Editor
Language
Summary Language
Original Title
Series Editor
Series Title
Abbreviated Series Title
Series Volume
Series Issue
Edition
ISSN
0003-0007
ISBN
Medium
Area
Expedition
Conference
Funding
Approved
$loc['no']
Call Number
COAPS @ mfield @
Serial
66
Permanent link to this record